2,903 research outputs found
Coexistence diameter in two-dimensional colloid-polymer mixtures
We demonstrate that the law of the rectilinear coexistence diameter in
two-dimensional (2D) mixtures of non-spherical colloids and non-adsorbing
polymers is violated. Upon approach of the critical point, the diameter shows
logarithmic singular behavior governed by a term t ln(t), with t the relative
distance from the critical point. No sign of a term t^2b could be detected,
with b the critical exponent of the order parameter, indicating a very weak or
absent Yang-Yang anomaly. Our analysis thus reveals that non-spherical particle
shape alone is not sufficient for the formation of a pronounced Yang-Yang
anomaly in the critical behavior of fluids.Comment: 4 pages, 4 figures, to appear in Phys. Rev. E (R
The interaction of amyloid A beta(1-40) with lipid bilayers and ganglioside as studied by P-31 solid-state NMR
Amyloid P-peptide (A beta) is a major component of plaques in Alzheimer's disease, and formation of senile plaques has been suggested to originate fro m regions of neuronal membrane rich in gangliosides. We analyzed the mode of interaction of A beta with lipid bilayers by multinuclear NMR using P-31 nuclei. We found that A beta (1-40) strongly perturbed the bilayer structure of dimyristoylphosphatidylcholine (DMPQ, to form a non-lamellar phase (most likely micellar). The ganglioside GM1 potentiated the effect of A beta (1-40), as viewed from P-31 NMR. The difference of the isotropic peak intensity between DMPC/A beta and DMPC/GM1/A beta suggests a specific interaction between A beta and GM1. We show that in the DMPC/GM1/A beta system there are three lipid phases, namely a lamellar phase, a hexagonal phase and non-oriented lipids. The latter two phases are induced by the presence of the A beta peptide, and facilitated by GM1. 9) 2008 Elsevier Ireland Ltd. All rights reserved
Flexible substrate for printed wiring
A very flexible substrate for printed wiring is disclosed which is composed of a blend of phenoxy resin-polyisocyanate-brominated epoxy resin in which the equivalent ration of the functional groups is hydroxyl grouped: isocyanate group: epoxy group = 1:0.2 to 2:0.5 to 3. The product has outstanding solder resistance and is applied to metal without using adhesives
Flexible composite film for printed circuit board
A flexible printed circuit for a printed circuit board in which layers of reaction product composed of a combination of phenoxy resin - polyisocyanate - brominated epoxy resin, and in which the equivalent ratio of those functional groups is hydroxyl group: isocyanate group: epoxy group - 1 : 0.2 to 2 : 0.5 to 3 are laminated on at least one side of saturated polyester film is discussed
Supersaturated dispersions of rod-like viruses with added attraction
The kinetics of isotropic-nematic (I-N) and nematic-isotropic (N-I) phase
transitions in dispersions of rod-like {\it fd}-viruses are studied.
Concentration quenches were applied using pressure jumps in combination with
polarization microscopy, birefringence and turbidity measurements. The full
biphasic region could be accessed, resulting in the construction of a first
experimental analogue of the bifurcation diagram. The N-I spinodal points for
dispersions of rods with varying concentrations of depletion agents (dextran)
were obtained from orientation quenches, using cessation of shear flow in
combination with small angle light scattering. We found that the location of
the N-I spinodal point is independent of the attraction, which was confirmed by
theoretical calculations. Surprisingly, the experiments showed that also the
absolute induction time, the critical nucleus and the growth rate are
insensitive of the attraction, when the concentration is scaled to the distance
to the phase boundaries.Comment: 13 pages, 14 figures. accepted in Phsical Review
Structure and thermodynamics of colloid-polymer mixtures: a macromolecular approach
The change of the structure of concentrated colloidal suspensions upon
addition of non-adsorbing polymer is studied within a two-component,
Ornstein-Zernicke based liquid state approach. The polymers' conformational
degrees of freedom are considered and excluded volume is enforced at the
segment level. The polymer correlation hole, depletion layer, and excess
chemical potentials are described in agreement with polymer physics theory in
contrast to models treating the macromolecules as effective spheres. Known
depletion attraction effects are recovered for low particle density, while at
higher densities novel many-body effects emerge which become dominant for large
polymers.Comment: 7 pages, 4 figures; to be published in Europhys. Let
Discrete elastic model for stretching-induced flagellar polymorphs
Force-induced reversible transformations between coiled and normal polymorphs
of bacterial flagella have been observed in recent optical-tweezer experiment.
We introduce a discrete elastic rod model with two competing helical states
governed by a fluctuating spin-like variable that represents the underlying
conformational states of flagellin monomers. Using hybrid Brownian dynamics
Monte-Carlo simulations, we show that a helix undergoes shape transitions
dominated by domain wall nucleation and motion in response to externally
applied uniaxial tension. A scaling argument for the critical force is
presented in good agreement with experimental and simulation results.
Stretching rate-dependent elasticity including a buckling instability are
found, also consistent with the experiment
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